Rule 1: 1. One and two
وَاحِدٌ and اِثْنَانِ are ordinary adjectives: they follow the noun and agree with it in gender and case. Since the dual already says two, اِثْنَانِ is added only for emphasis or stands alone, as in an answer to كَمْ. The related أَحَدُ (feminine إِحْدَى) means one of and is followed by a definite genitive plural.
لِي كِتَابٌ وَاحِدٌ وَسَاعَةٌ وَاحِدَةٌ.
lī kitābun wāḥidun wa-sāʿatun wāḥidatun
I have one book and one watch.
كَمْ نَجْمًا رَأَيْتَ؟ - رَأَيْتُ اثْنَيْنِ.
kam najman raʾayta? - raʾaytu-thnayni
How many stars did you see? I saw two.
After كَمْ the noun is accusative singular (lesson 50); اِثْنَيْنِ stands alone as the object.
فِي الْبَيْتِ وَلَدَانِ اثْنَانِ لَا ثَلَاثَةٌ.
fi-l-bayti waladāni-thnāni lā thalāthatun
In the house there are two boys, not three.
اِثْنَانِ added for emphasis after the dual.
جَاءَ أَحَدُ الْأَوْلَادِ مَعَ إِحْدَى الْبَنَاتِ.
jāʾa aḥadu-l-awlādi maʿa iḥda-l-banāti
One of the boys came with one of the girls.